CONCEPT RECAPITULATION TEST - IV Paper 1 [ANSWERS, HINTS & SOLUTIONS]

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  • AITS-CRT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/14
    FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
    website: www.fiitjee.com
    1
    ANSWERS, HINTS & SOLUTIONS
    CRT –IV
    (Paper-1)
    Q.
    No.
    PHYSICS CHEMISTRY MATHEMATICS
    1.
    A B C
    2.
    A A D
    3.
    B D A
    4.
    D C A
    5.
    C C A
    6.
    D B D
    7.
    D A A
    8.
    D C A
    9.
    B A D
    10.
    C C A
    11.
    B, C
    C, D
    A, B, D
    12.
    A, B, C
    A, C
    A, B, D
    13.
    A, B
    A, B, C, D
    A, B
    14.
    B, C
    A, D
    B, D
    15.
    A, D
    A, D
    A, D
    1.
    8 2 2
    2.
    0 3 2
    3.
    2 3 4
    4.
    4 3 1
    5.
    1 8 4
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    Page 1

  • AITS-CRT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/14
    FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
    website: www.fiitjee.com
    2
    P
    P
    h
    h
    y
    y
    s
    s
    i
    i
    c
    c
    s
    s PART – I
    1. There will be no change.
    h = h
    h
    A
    2. =
    v
    A
    – v
    B
    =
    0 0
    (b) (a)
    W = Q(v
    A
    v
    B
    ) =
    0
    Q
    (b a)
    3. = 0 + 1 10 = 10 rad/sec
    2
    v = r = 1 10 = 10 m/s
    0
    3
    q(v r )
    B
    r
    |B |
    =
    0
    2
    qv
    4 r
    B =
    7
    2
    10 0.1 10
    (1)
    = 10
    -7
    T
    4. conservation of momentum
    M 2gh m 2gh
    =MV
    1
    + mV
    2
    (1)
    1 2
    V V
    1
    2 2gh
    (2)
    2
    V 3 2gh
    2
    2
    V
    h' 9h
    2g
    5.
    1 2
    1 1 1
    C C C
    =
    0 0
    x a b x
    A A
    C =
    0
    A
    a b
    6. FBD of ‘B’ and ‘C’
    a B
    2g
    T
    a
    C
    3g
    T
    T – 2g = 2a . . . (i)
    and 3g – T = 3a . . . (ii)
    T =
    12g
    5

    Page 2

  • AITS-CRT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/14
    FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
    website: www.fiitjee.com
    3
    for A
    a
    A
    mg
    T=2T
    T = mg
    2
    12g
    5
    = mg m = 4.8 kg.
    7. W =
    / 2
    0
    mgR
    f.Rd
    2
    = 1 joule.
    9. a =
    v g a m g a
    m
    = 20 m/s
    2
    t =
    2h
    a
    = 1 sec
    11. Angular momentum =
    nh
    2
    kinetic energy
    2
    1
    n
    De-broglie wavelength =
    h
    mv
    so as v increases decreases.
    14. Relative velocity of B w.r.t. A along vertical direction should be zero
    20 sin = 10
    sin =1/2
    x = 20 cos 30
    1
    2
    =
    5 3
    m
    15. Change in angular momentum = angular impulse
    L = 5
    I =
    2
    ma
    3
    K =
    2 2
    L 75
    2I 2ma
    Section -C
    1. Conservation of energy
    2
    1 3
    mv mg mg m 3 2
    2 2 2 2
    g
    v 8g
    60
    2. Potential across capacitor is zero, hence energy stored is zero.
    3. v
    A
    – v
    B
    = E. dx = 10 (1)
    = 10 volt.

    Page 3

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    4
    4. Z =
    2 2
    R X
    =
    2
    9 X
    but cos =
    R 3
    Z 5
    X = 4 .
    5.
    E
    2
    = E – ir
    i =
    E
    2r
    . . . (i)
    2E = i(3 + r) . . . (ii)
    r = 1

    Page 4

  • AITS-CRT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/14
    FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
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    5
    C
    C
    h
    h
    e
    e
    m
    m
    i
    i
    s
    s
    t
    t
    r
    r
    y
    y PART – II
    SECTION – A
    1. K
    c
    = 4 × 10
    -19
    1
    2
    Ag 2CN Ag CN
    0.03 0.1 0
    1
    2
    Ag CN Ag 2CN
    t 0 0.3 0 0.04
    0.03 x x 0.04 2x
    2
    19
    c
    x 0.04 2x
    K 4 10
    0.03 x
    0.04 2x 0.04
    0.03 x 0.03
    2
    19
    c
    x. 0.04
    K 4 10
    0.03
    x = 7.5 × 10
    -18
    2. PV = nRT
    As PV constant
    n
    1
    T
    1
    = n
    2
    T
    2
    n
    1
    . 300 = n
    2
    . 400
    n
    2
    =
    1
    300
    n
    400
    1
    3
    n
    4
    4. Energy of
    e
    in H-atom = - E
    Energy of
    e
    in Li
    +2
    = - 9E
    Energy supplied by photon =
    2
    1
    IE mv
    2
    IE |E |
    2
    p
    1
    E 9E mv
    2
    p
    2 E 9E
    v
    m
    9.
    4 2 3 3 2
    FeSO Fe O SO SO
    
    12.
    o
    2
    1
    H e H E 0.0 v
    2
    
    2
    H /H
    0.059 1
    E E 0 log
    1
    H
    0.059 7 0.413
    So,
    2
    2
    H /H Ni /Ni
    E E
    Ni will deposit at cathode
    2 2
    2H O 2e H 2OH
    

    Page 5

  • AITS-CRT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/14
    FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
    website: www.fiitjee.com
    6
    2
    0.059
    E 0.83 log OH
    2
    0.83 0.059 7
    = - 0.417
    13. Both have Cr
    +3
    (d
    3
    ), and C.N. is 6. Hence d
    2
    sp
    3
    .
    Pd
    +2
    (d
    8
    ) complexes with C.N. is 4 are square plannar and magnetic moment is zero.
    14.
    3 2 2
    FeCl FeCl Cl
    Dil. CuCl
    2
    is blue due to [Cu(H
    2
    O)
    4
    ]
    2+
    PH
    3
    is obtained by heating white P with NaOH
    All are reducing because of weak P – H bond.
    SECTION – C
    1.
    A =
    H
    2
    C
    CH
    3
    Br
    C =
    CH
    3
    Br
    Br
    CH
    3
    B =
    Br
    CH
    3
    Br
    CH
    3
    E =
    CH
    3
    Br
    CH
    2
    Br
    D =
    inactive
    2.
    3
    KNO
    22
    2
    1
    OKNO
    223
    2
    1
    ONaNONaNO
    23
    )(2 NOPb
    2
    22
    4 ONOPbO
    2
    3
    2
    3
    , NOSrNOCa ,
    34
    NONH
    OHON
    22
    2
    23
    )(NOPb do not respond to the test.
    23
    )(2 NOCa
    22
    42 ONOSrO
    2
    3
    2 NOMg
    22
    42 ONOMgO
    3.
    O S
    O
    O
    H S OH
    O
    4.
    b b
    T K m i
    2.08 = 0.52 × 1 × i
    i = 4
    3
    6
    K Fe CN

    Page 6

  • AITS-CRT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/14
    FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
    website: www.fiitjee.com
    7
    5.
    Cl Cl
    Cl Cl
    
    
    OH OH
    OH OH
    O
    O
    X
    Y
    Z

    Page 7

  • AITS-CRT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/14
    FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
    website: www.fiitjee.com
    8
    M
    M
    a
    a
    t
    t
    h
    h
    e
    e
    m
    m
    a
    a
    t
    t
    i
    i
    c
    c
    s
    s PART – III
    1.
    1 1
    2 1
    I x 1 1 1 dx x 1 0 1 dx
    2. Here,
    1
    f x , if 0 x
    2
    1 1
    g x f , if x 1
    2 2
    3 x , if 1 x 2
    4. Let
    A
    CAD
    3
    By m – n theorem,
    (1 + 1) cot = 1 cot 2 – 1cot
    A
    B
    C
    D
    2
    6. Here, z
    2
    – z
    3
    = i(z
    1
    – z
    3
    )
    ACB
    2
    13
    AC
    2
    ; AC = BC
    9. (0, 0) lies on the director circle
    10.
    1/ 3 1/ 2
    2/ 3 1/ 3 1/ 2
    x 1 x 1
    x x
    x x 1 x x
    12.
    1 1
    3
    a b 1 1 1
    a b
    x y z 3 ;
    2 x y z 2
    14. Here, f
    –1
    (x) =
    a x a
    SECTION – C
    1. Equation of tangent is
    y f' x
    Also,
    2
    f '
    f ' 1
    Thus,
    2 2
    dy 1 y x
    dx 2 xy
    Thus, equation of curve is x
    2
    + y
    2
    – 2x = 0
    2. Equation of normal is
    n
    n 1
    1
    y a x a
    na

    Page 8

  • AITS-CRT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/14
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    website: www.fiitjee.com
    9
    4. Here,
    1
    = d(a
    1
    – a
    2
    )(a
    2
    – a
    3
    )(a
    3
    – a
    1
    ) = –2d
    4
    Also,
    2
    = –2d
    4
    5. sin
    2
    x[sin
    2
    x + sin x + 2] = 0
    sin x = 0, where x = 0, , 2, 3

    Page 9

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